THE CONCENTRATED SOLUTION VISCOSITY OF GR-S: ITS VARIATION (IN BENZENE) WITH TEMPERATURE AND CONCENTRATION

Abstract

With a falling ball viscometer, measurements of the viscosity of solutions of GR–S in benzene have been made at very low rates of shear, at concentrations ranging from 10 to 19%, and at temperatures ranging from 10° to 35 °C. Within these limits, the viscosity of a solution of GR–S in benzene is given by the equation [Formula: see text]. Extrapolation, by means of this equation, to 100% polymer yields a value of 13.0 kcal. per mole for the energy of activation of flow of GR–S; this value, though of dubious antecedence, is yet of interest because it approximates that expected for GR–S on the basis of the behavior of such polymers as natural rubber and polystyrene.