Synthesis of short-cellular analogues of polyphenylenevinylene based on amino-substituted biphenyl and dibenzotiofen

Author:

Halinouski N. A.1,Petushok V. G.1,Kalechyts G. V.1

Affiliation:

1. Institute of Chemistry of New Materials of the National Academy of Sciences of Belarus, Minsk

Abstract

Synthesis of new asymmetric poly-π-conjugated amino derivatives of biphenyl and 3,5-dioxodibenzothiophene containing phenylethyl and fluorophenyl ethenyl fragments in the main chain of conjugation and cyclic fragments as the central chromophore was conducted. Due to the presence of alkylamine substituents, a bathochromic shift (by 15–25 nm) is observed for all the synthesized compounds in comparison with compounds that do not have alkylamine substituents. The compounds obtained are blue phosphorescent luminophores.

Publisher

Publishing House Belorusskaya Nauka

Subject

Inorganic Chemistry,Organic Chemistry,Chemistry (miscellaneous),Analytical Chemistry

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