Diradical character in strained molecules accelerates bioisostere synthesis

Author:

Fernando Shehan H.,Migliaro Ignacio,Sterling Alistair J.

Funder

The University of Texas at Dallas

Publisher

Elsevier BV

Reference10 articles.

1. The concept of strain in organic chemistry;Wiberg;Angew. Chem. Int. Ed.,1986

2. Beyond strain release: delocalization-enabled organic reactivity;Sterling;J. Organomet. Chem.,2024

3. From mechanism to mouse: a tale of two bioorthogonal reactions;Sletten;Acc. Chem. Res.,2011

4. The role of aryne distortions, steric effects, and charges in regioselectivities of aryne reactions;Medina;J. Am. Chem. Soc.,2014

5. σ-Bond insertion reactions of two strained diradicaloids;Meza;Nature,2025

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