The isomerization of optically-active propargyl alcohols to terminal acetylenes.
Author:
Publisher
Elsevier BV
Subject
Organic Chemistry,Drug Discovery,Biochemistry
Reference14 articles.
1. Saline hydrides and superbases in organic reactions. IX. Acetylene zipper. Exceptionally facile contrathermodynamic multipositional isomeriazation of alkynes with potassium 3-aminopropylamide
2. Exceptionally easy isomerization of acetylenic alcohols with potassium 3-aminopropylamide. A new, high yield synthesis of functionally differentiated αω-difunctional structures
3. Novel synthesis of an ω-alkynylorganometallic reagent via triple bond isomerization with potassium 3-aminopropylamide: ω-(9-borabicyclo[3.3.1]nonan-9-yl)alkl-1-ynes
4. Reduction of .alpha.,.beta.-acetylenic ketones with B-3-pinanyl-9-borabicyclo[3.3.1]nonane. High asymmetric induction in aliphatic systems
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