The nature of the interaction of nucleophiles such as HMPT, DMSO, DMF and Ph3PO with triorganohalo-silanes, -germanes, and -stannanes and organophosphorus compounds. Mechanism of nucleophile induced racemization and substitution at metal-Reference-Cited by-同舟云学术

The nature of the interaction of nucleophiles such as HMPT, DMSO, DMF and Ph3PO with triorganohalo-silanes, -germanes, and -stannanes and organophosphorus compounds. Mechanism of nucleophile induced racemization and substitution at metal

Published:1980-02 Issue:1 Volume:186 Page:25-37
ISSN:0022-328X
Container-title:Journal of Organometallic Chemistry
language:en
Short-container-title:Journal of Organometallic Chemistry

Author:

Corriu R.J.P.,Dabosi G.,Martineau M.

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference22 articles.

1. The nature of the interaction between hexamethyl-phosphortriamide and trimethylhalosilanes; cations containing tetracovalent silicon as possible intermediates in nucleophile-induced substitution of silicon halides

2. Mécanisme de la racémisation des chlorosilanes. Étude cinétique: Détermination de l'ordre et de l'entropie d'activation

3. The siliconium ion question

4. Problème du cation siliconium V. Mécanisme de la racémisation de chlorosilanes et de chlorogermanes diversement encombrés

5. Organometallic compounds

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