Conjugated and electroluminescent polymers
Author:
Publisher
Elsevier BV
Subject
Colloid and Surface Chemistry,Polymers and Plastics,Physical and Theoretical Chemistry,Surfaces and Interfaces
Reference46 articles.
1. Baldo MA, Obrien DF, You Y, Shoustikov A, Sibley S, Thompson ME, Forrest SR: Highly efficient phosphorescent emission from organic electroluminescent devices. Nature 1998, 395:151.⋅⋅This is an outstanding paper, showing a clever approach to high efficiency LEDs via access to triplets photophysics, it is simple, since it uses `trivial' doping of a phosphorescent dye into an electroactive host, yet very ingenious, in the choice of the dye and of the device structure. It also gives a number of hints and suggestions, for future experiments, aimed at further optimisation of the devices and at a better understanding of the properties of triplets in organic semiconductors.
2. Cleave V, Yahioglu G, Le Barny P, Friend RH, Tessler N: Harvesting singlet and triplet energy in polymer LEDs. Adv Mat 1998, in press.⋅⋅Another excellent paper are made on the triplets photophysics, which confirms the results of [1], but by making use of a polymeric host. Further suggestions on how to use LEDs and polymer/dyes blends to probe triplet energies.
3. Bach U, Lupo D, Comte P, Moser JE, Weissortel F, Salbeck J, Spreitzer H, Gratzel M: Solid-state dye-sensitised mesoporous TiO2 solar cells with high photon-to-electron conversion efficiencies. Nature 1998, 395:583.⋅⋅An elegant demonstration of how solid thin films of organic semiconductors can provide high-quality, flexible and technologically robust contributions to a variety of applications requiring charge transport. In this case a spiro-linked phenyl-amine based molecule substitutes a liquid electrolyte, improving processibility and device performance.
4. Granström M, Petritsch K, Arias AC, Lux A, Andersson MR, Friend RH: Laminated fabrication of polymeric photovoltaic diodes. Nature 1998, 395:257.⋅⋅This paper describes a method to extend control over the morphology of polymer mixtures without losing the benefits of a diffuse junction between heterogeneous polymers, and at the same time taking advantage of the peculiarity of the materials, such as the tendency of 2 polymer films to interpenetrate when they are pressed together at moderately high temperature. The paper highlights a theme, namely that of the importance of the control of morphology in view of electro-optical properties, which is likely to become dominant in the near future.
5. Chua BS, Cacialli F, Davies JE, Feeder N, Friend RH, Holmes AB, Marseglia EA, Moratti SC, Brédas J-L, dos Santos DA: New luminescent PPV derivatives for LED applications. Mat Res Soc Symp Proc: Symposium J 1998, 488:87.
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