Author:
Umar Adaji Mohammed,Saviour Iorungwa Moses,Wasiu Salawu Olalekan
Abstract
Schiff bases, derivatives born from the condensation of primary amines with carbonyl compounds, have long captured the attention of chemists due to their intriguing structural, biological, and coordination properties. The versatility of these compounds is evident in their wide array of applications ranging from medicinal chemistry to coordination-driven processes and material science. This chapter provides an exhaustive exploration into the synthesis, characterization, and applications of Schiff base ligands and their metal complexes. Emphasis is laid on the myriad ways Schiff bases can be tailored to design metal complexes with specific properties, opening doors to targeted applications. Through a blend of fundamental principles, modern characterization techniques, and real-world applications, readers will gain a holistic understanding of Schiff base chemistry, its interplay with metals, and its bearing on various scientific and industrial domains. This comprehensive guide serves as a testament to the adaptability and significance of Schiff bases in contemporary chemical research and development.
Reference25 articles.
1. Adaji MU, Wuana RA, Itodo AU, Eneji IS, Iorungwa MS. Metal complexes of (E) – N1- (2 -hydroxybenzylidene)nicotinohydrazide Schiff base; Synthesis, characterization and nematicidal activity. Arabian Journal of Chemical and Environmental Research. 2022;9(1):1-27
2. Aminu IH, Aliyu HN, Musa H, Dayyib AS. Synthesis, Characterization and antimicrobial studies on Mn(II), Fe(II), Co(II) complexes of Schiff base derived from 3-Formylchromone and Benzohydrazide. Algerian Journal of. Engineering and Technology. 2021;4:81-89. Available from: http://jetjournal.org/index.php/ajet/article/view/45
3. Maity S, Shyamal M, Das D, Mazumdar P, Sahoo GP, Misra A. Aggregation induced emission enhancement from antipyrine-based Schiff base and its selective sensing towards picric acid. Sensors and Actuators B: Chemical. 2017;248:223-233. DOI: 10.1016/j.snb.2017.03.161
4. Pawlica D, Marszałek M, Mynarczuk G, Sieroń L, Eilmes J. New unsymmetrical Schiff base Ni(II) complexes as scaffolds for dendritic and amino acid superstructures. New Journal of Chemistry. 2004;28:1615-1621
5. Ahmad N, Alam M, Wahab R, Ahmed M, Ahmad A. Synthesis, spectral and thermo-kinetics explorations of Schiff-base derived metal complexes. Open Chemistry. 2020;18(1):1304-1315. DOI: 10.1515/chem-2020-0168