Author:
Aroney MJ,Bruce EAW,John IG,Radom L,Ritchie GLD
Abstract
Ab initio molecular
orbital theory has been used to deduce the preferred gas-phase conformations of
vinyl formate and vinyl acetate. In addition, experimental dipole moments (1030μ/Cm)
and molar Kerr constants (1027mK/m5 V-2 mol-1)
at 25�C are reported for both molecules as solutes in carbon tetrachloride:
vinyl formate (5.07, + 48.1) and vinyl acetate (5.70, + 3.8). The preferred
solution-state conformations indicated by the analysis of these results are
shown to be consistent with the theoretical predictions.
Cited by
22 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献