The diffusion of aluminium and gallium in zinc oxide

Author:

Norman VJ

Abstract

Solubilities and rates of substitutional diffusion of aluminium and gallium in polycrystalline zinc oxide have been determined in the temperature range 750-1000� by a chemical method previously described. The solubility of aluminium in zinc oxide, expressed in ions cm-3, is given by the expression n = 1.0 x 1023exp(-1.08k-1T-1), and the solubility of gallium by n = 2.7 x 1021exp(-0.59k-1T-1), where the activation energies are expressed in eV. The rates of diffusion of both aluminium and gallium were found to be dependent on surface concentration up to a limiting value, at which the diffusion coefficient of aluminium is D = 5.3 x 10-2 exp(-2.74k-1T-1) cm2 sec-1, and that of gallium is D = 3.6 x 104 exp(-3.75k-1T-1) cm2 sac-1. ��� It is shown that supersaturation of both aluminium and gallium in the zinc oxide crystals occurs above 800�.

Publisher

CSIRO Publishing

Subject

General Chemistry

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3