Remote Quantitative Analysis of Minerals Based on Multispectral Line-Calibrated Laser-Induced Breakdown Spectroscopy (LIBS)

Author:

Wan Xiong12,Wang Peng2

Affiliation:

1. Key Laboratory of Space Active Opto-Electronics Tehcnology, Shanghai Institute of Technical Physics of the Chinese Academy of Sciences, Shanghai 200083, China

2. Key Laboratory of Nondestructive Testing (Ministry of Education), Nanching Hangkong University, Nanchang 330063, China

Abstract

Laser-induced breakdown spectroscopy (LIBS) is a feasible remote sensing technique used for mineral analysis in some unapproachable places where in situ probing is needed, such as analysis of radioactive elements in a nuclear leak or the detection of elemental compositions and contents of minerals on planetary and lunar surfaces. Here a compact custom 15 m focus optical component, combining a six times beam expander with a telescope, has been built, with which the laser beam of a 1064 nm Nd; YAG laser is focused on remote minerals. The excited LIBS signals that reveal the elemental compositions of minerals are collected by another compact single lens-based signal acquisition system. In our remote LIBS investigations, the LIBS spectra of an unknown ore have been detected, from which the metal compositions are obtained. In addition, a multi-spectral line calibration (MSLC) method is proposed for the quantitative analysis of elements. The feasibility of the MSLC and its superiority over a single-wavelength determination have been confirmed by comparison with traditional chemical analysis of the copper content in the ore.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

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