Temperature Measurement in a CO2 Laser Beam by Laser-Induced Fluorescence of O2

Author:

Lalo C.1,Masanet J.1,Deson J.1,Ben-Aim R.1,Rostas J.1

Affiliation:

1. Laboratoire de Chimie Générale, UPMC-CNRS URA 40870, Tour 55, 4e Etage, 4 Place Jussieu, 75252 Paris Cedex 05, France (C.L., J.M., J.D., R.B.-A.); and Laboratoire de Photophysique Moléculaire du CNRS and IPCM de L'Université Paris-Sud, Be 213, Université de Paris-Sud, 91405 Orsay, France (J.R.)

Abstract

A mixture of SF6-O2 is irradiated by an infrared (10.6 μm) cw CO2 laser. Absorption by SF6, and subsequent collisional energy transfer, heats the mixture. Vibrationally excited ground-state O2 is detected at levels v = 0, 1, and 2 by laser-induced fluorescence in the B3 Σu X3Σ8 – Schumann-Runge system with an ArF laser (193.3 nm). Comparison of the observed LIF spectrum with spectra simulated at various temperatures shows that the molecular oxygen in the IR laser beam is thermalized at a temperature of about 700 K.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

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