Characterization and thermal behavior of some types of kaolin of different origin from Northern Vietnam

Abstract

Kaolin (mainly composed of kaolinite, whose chemical formula is Al2Si2O5(OH)4), serves as a versatile raw material widely used in various industries including production of ceramics, paper, paints, cosmetics, pneumatics, building materials, and hazardous waste storage. In the northern part of Vietnam, due to favorable geological conditions, there are diverse deposits of high quality kaolin of different origin and scale. Decades of research indicate the diversity of kaolin sources in the region, with special attention paid to hydrothermally altered and exchange types of kaolin, the formation of which is associated with complex processes of weathering, hydrothermal alteration and reprecipitation. The aim of this study was to characterize three different types of kaolin derived from different sources in Northern Vietnam (from weathered pegmatites, weathered felsic effusives, and hydrothermal-metasomatic altered rocks). The main focus was to analyze the thermal behavior of these samples during calcination in the temperature range from 300 °C to 1,100 °C. The comprehensive characterization was performed by X-ray diffraction (XRD), FT-IR spectroscopy (FT-IR), thermal analysis (thermogravimetry / differential thermogravimetry (TG / DTG)) and scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDS). The results showed that kaolinite with particle size less than 2 μm was identified in all samples. Minor amounts of muscovite and montmorillonite are present in some samples, and pyrophyllite is present in a sample from the hydrothermally altered rocks. Kaolinite morphology in all the samples showed typical forms including hexagonal and pseudohexagonal. The main chemical constituents of the samples are SiO2 and Al2O3; in addition to these, K2O + Na2O, TiO2 and iron are present in smaller quantities. Thermal analysis allowed to reveal the formation of metakaolinite phase at temperatures around 494 °C and 507 °C in the two studied samples from weathered rocks, while the pyrophyllite-bearing sample undergoes this transition at a higher temperature of 653.8 °C. The onset of metakaolinization was observed at about 500 °C for the weathered rock samples and about 700 °C for the pyrophyllite-bearing sample. In addition, mullitization leading to the formation of mullite was evident at 1,100 °C. The study findings allow concluding that the studied kaolins can be used in traditional ceramics production.