A chlorine-free protocol for processing germanium

Author:

Glavinović Martin1,Krause Michael2,Yang Linju3,McLeod John A.3ORCID,Liu Lijia3,Baines Kim M.23,Friščić Tomislav1,Lumb Jean-Philip1

Affiliation:

1. Department of Chemistry, McGill University, 801 Sherbrooke Street West, Montreal, Quebec H3A 0B8, Canada.

2. Department of Chemistry, University of Western Ontario, 1151 Richmond Street, London, Ontario N6A 5B7, Canada.

3. Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Institute of Functional Nano and Soft Materials (FUNSOM) and Soochow University–Western University Center for Synchrotron Radiation Research, Soochow University, Suzhou, Jiangsu 215123 China.

Abstract

A quinone/catechol redox platform replaces Cl 2 or HCl for processing germanium metal or germanium dioxide to germanes.

Funder

Natural Sciences and Engineering Research Council of Canada

National Natural Science Foundation of China

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference42 articles.

1. On the materials basis of modern society

2. A simple primary amide for the selective recovery of gold from secondary resources;Doidge E. D.;Angew. Chem., Int. Ed.,2016

3. J. J. Moore in Chemical Metallurgy (Butterworth-Heinemann ed. 2 1990) pp. 243–309.

4. P. Schmittinger T. Florkiewicz L. Calvert Curlin B. Lüke R. Scannell T. Navin E. Zelfel R. Bartsch Chlorine in Ullmann’s Encyclopedia of Industrial Chemistry (Wiley-VCH Verlag GmbH & Co. KGaA 2000) pp. 532–622.

5. The life-cycle of chlorine, Part I: Chlorine production and the chlorine-mercury connection;Ayers R.;J. Ind. Ecol.,1997

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