A physical catalyst for the electrolysis of nitrogen to ammonia

Author:

Song Yang1ORCID,Johnson Daniel1,Peng Rui1,Hensley Dale K.1,Bonnesen Peter V.1,Liang Liangbo1ORCID,Huang Jingsong12ORCID,Yang Fengchang3,Zhang Fei3,Qiao Rui3ORCID,Baddorf Arthur P.1ORCID,Tschaplinski Timothy J.4,Engle Nancy L.4,Hatzell Marta C.5ORCID,Wu Zili16,Cullen David A.7ORCID,Meyer Harry M.7,Sumpter Bobby G.12,Rondinone Adam J.1ORCID

Affiliation:

1. Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA.

2. Computational Sciences and Engineering Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA.

3. Virginia Polytechnic Institute and State University, Blacksburg, VA 24061, USA.

4. Biosciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA.

5. George W. Woodruff School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, GA 30332, USA.

6. Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA.

7. Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA.

Abstract

A nanostructured, carbon-based physical catalyst electrochemically reduces N 2 to ammonia under ambient conditions.

Funder

Basic Energy Sciences

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference54 articles.

1. U.S. Geological Survey Mineral Commodity Summaries 2016 (U.S. Geological Survey 2016).

2. Towards an ammonia-mediated hydrogen economy?;Christensen C. H.;Catal. Today,2006

3. Catalytic reduction of dinitrogen to ammonia by molybdenum: Theory versus experiment;Schrock R. R.;Angew. Chem. Int. Ed. Engl.,2008

4. Challenges in reduction of dinitrogen by proton and electron transfer;van der Ham C. J. M.;Chem. Soc. Rev.,2014

5. Photo-illuminated diamond as a solid-state source of solvated electrons in water for nitrogen reduction

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