Enhancement of lithium-mediated ammonia synthesis by addition of oxygen

Abstract

Boosting ammonia with a little oxygen Ammonia synthesis from nitrogen for fertilizer production is highly energy intensive. Chemists are therefore exploring electrochemical approaches that could draw power from renewable sources while generating less waste. One promising cycle involves the reduction of lithium ions at an electrode, with the resultant metal in turn reducing nitrogen and regenerating the ions. Li et al . report the counterintuitive result that small quantities of oxygen could enhance the efficiency of this process, which they attribute to diffusional effects that limit excessive lithium reduction. —JSY