Metastable Dion-Jacobson 2D structure enables efficient and stable perovskite solar cells

Author:

Zhang Fei1ORCID,Park So Yeon1ORCID,Yao Canglang23ORCID,Lu Haipeng1ORCID,Dunfield Sean P.456ORCID,Xiao Chuanxiao4ORCID,Uličná Soňa7ORCID,Zhao Xiaoming8ORCID,Du Hill Linze9ORCID,Chen Xihan1ORCID,Wang Xiaoming23,Mundt Laura E.7ORCID,Stone Kevin H.7ORCID,Schelhas Laura T.17ORCID,Teeter Glenn4ORCID,Parkin Sean10ORCID,Ratcliff Erin L.91112ORCID,Loo Yueh-Lin8ORCID,Berry Joseph J.4513ORCID,Beard Matthew C.1ORCID,Yan Yanfa23ORCID,Larson Bryon W.1ORCID,Zhu Kai1ORCID

Affiliation:

1. Chemistry and Nanoscience Center, National Renewable Energy Laboratory, Golden, CO 80401, USA.

2. Department of Physics and Astronomy, University of Toledo, Toledo, OH 43606, USA.

3. Wright Center for Photovoltaics Innovation and Commercialization, University of Toledo, Toledo, OH 43606, USA.

4. Materials Science Center, National Renewable Energy Laboratory, Golden, CO 80401, USA.

5. Renewable and Sustainable Energy Institute, University of Colorado, Boulder, CO 80309, USA.

6. Materials Science and Engineering Program, University of Colorado, Boulder, CO 80309, USA.

7. SLAC National Accelerator Laboratory, Menlo Park, CA 94025, USA.

8. Department of Chemical and Biological Engineering, Princeton University, Princeton, NJ 08544, USA.

9. Department of Chemical and Environmental Engineering, University of Arizona, Tucson, AZ 85721, USA.

10. Department of Chemistry, University of Kentucky, Lexington, KY 40506, USA.

11. Department of Chemistry and Biochemistry, University of Arizona, Tucson, AZ 85721, USA.

12. Department of Materials Science and Engineering, University of Arizona, Tucson, AZ 85721, USA.

13. Department of Physics, University of Colorado, Boulder, CO 80309, USA.

Abstract

Directing efficient hole transport Surface defects in three-dimensional perovskites can decrease performance but can be healed with coatings based on two-dimensional (2D) perovskite such as Ruddlesden-Popper phases. However, the bulky organic groups of these 2D phases can lead to low and anisotropic charge transport. F. Zhang et al . show that a metastable polymorph of a Dion-Jacobson 2D structure based on asymmetric organic molecules reduced the energy barrier for hole transport and their transport through the layer. When used as a top layer for a triple-cation mixed-halide perovskite, a solar cell retained 90% of its initial power conversion efficiency of 24.7% after 1000 hours of operation at approximately 40°C in nitrogen. —PDS

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3