Transparent, Conductive Carbon Nanotube Films

Author:

Wu Zhuangchun123,Chen Zhihong123,Du Xu123,Logan Jonathan M.123,Sippel Jennifer123,Nikolou Maria123,Kamaras Katalin123,Reynolds John R.123,Tanner David B.123,Hebard Arthur F.123,Rinzler Andrew G.123

Affiliation:

1. Department of Physics, University of Florida, Gainesville, FL 32611, USA.

2. Department of Chemistry, University of Florida, Gainesville, FL 32611, USA.

3. MTA SzFKI, Budapest, H 1525, Hungary.

Abstract

We describe a simple process for the fabrication of ultrathin, transparent, optically homogeneous, electrically conducting films of pure single-walled carbon nanotubes and the transfer of those films to various substrates. For equivalent sheet resistance, the films exhibit optical transmittance comparable to that of commercial indium tin oxide in the visible spectrum, but far superior transmittance in the technologically relevant 2- to 5-micrometer infrared spectral band. These characteristics indicate broad applicability of the films for electrical coupling in photonic devices. In an example application, the films are used to construct an electric field–activated optical modulator, which constitutes an optical analog to the nanotube-based field effect transistor.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference27 articles.

1. D. Ginleyet al., Mater. Res. Soc. Symp. Proc.668, H 2.7.1 (2001).

2. R. G. Gordon, MRS Bull.25, 52 (2000).

3. K. Leeet al., Nano Lett.4, 911 (2004).

4. See supporting text on Science Online.

5. Others have also used vacuum filtration as the initial step to fabricate free-standing SWNT films ( 6 ). However their transfer process involved cutting a rectangular hole in adhesive tape laying this tape onto the nanotube layer on the membrane and peeling up the tape to obtain the free-standing film within the hole in the tape. This gives comparatively little control over the film thickness and is not amenable to film deposition over large areas compatible with microelectronic processing.

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