Ordered macro-microporous metal-organic framework single crystals

Author:

Shen Kui1ORCID,Zhang Lei1,Chen Xiaodong1,Liu Lingmei2,Zhang Daliang3ORCID,Han Yu2ORCID,Chen Junying1ORCID,Long Jilan1,Luque Rafael4ORCID,Li Yingwei1ORCID,Chen Banglin5ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China.

2. Advanced Membranes and Porous Materials Center, Physical Sciences and Engineering Division, King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Saudi Arabia.

3. Imaging and Characterization Core Lab, KAUST, Thuwal 23955-6900, Saudi Arabia.

4. Departamento de Química Orgánica, Universidad de Córdoba, Edificio Marie Curie, Carretera Nacional IV-A, Km 396, E14014, Córdoba, Spain.

5. Department of Chemistry, University of Texas at San Antonio, One UTSA Circle, San Antonio, TX 78249, USA.

Abstract

Mesoporous metal-organic frameworks The diffusion limitations on gas storage and catalytic reaction of microporous materials can often be overcome if they are incorporated into a mesoporous structure with much larger pores. Shen et al. grew ordered arrays of microcrystals of the ZIF-8 metal-organic framework, in which zinc ions are bridged by 2-methylimidazole linkers, inside a porous polystyrene template. These materials showed higher reaction rates for the Knoevenagel reaction between benzaldehydes and malononitriles and better catalyst recyclability. Science , this issue p. 206

Funder

Welch Foundation

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3