Photochemical route for synthesizing atomically dispersed palladium catalysts-Reference-Cited by-同舟云学术

Photochemical route for synthesizing atomically dispersed palladium catalysts

Published:2016-05-13 Issue:6287 Volume:352 Page:797-800
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Liu Pengxin¹,Zhao Yun¹,Qin Ruixuan¹,Mo Shiguang¹,Chen Guangxu¹,Gu Lin²,Chevrier Daniel M.³,Zhang Peng³,Guo Qing¹,Zang Dandan¹,Wu Binghui¹,Fu Gang¹,Zheng Nanfeng¹

Affiliation:

1. State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, Engineering Research Center for Nano-Preparation Technology of Fujian Province, National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers, and Esters, and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.

2. Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China.

3. Department of Chemistry, Dalhousie University, Halifax, Nova Scotia B3H 4R2, Canada.

Abstract

Lightly dispersed palladium Catalysts made from atomically dispersed metal atoms on oxide supports can exhibit very high per atom activity. However, the low loadings needed to prevent metal particle formation can limit overall performance. Liu et al. stably decorated titanium oxide nanosheets with relatively high loadings of single palladium atoms by reducing the ions with ultraviolet light and ethylene glycol. These catalysts cleaved H 2 into atoms and were highly effective for hydrogenating alkenes and aldehydes. Science , this issue p. 797

Funder

Ministry of Science and Technology of China

National Natural Science Foundation of China

NSERC CGS Alexander Graham Bell

NSERC Discovery

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference54 articles.

1. Single-atom catalysis of CO oxidation using Pt1/FeOx

2. Identification of active sites in CO oxidation and water-gas shift over supported Pt catalysts