Identification of single-site gold catalysis in acetylene hydrochlorination

Author:

Malta Grazia1ORCID,Kondrat Simon A.1ORCID,Freakley Simon J.1ORCID,Davies Catherine J.1ORCID,Lu Li2ORCID,Dawson Simon1ORCID,Thetford Adam34ORCID,Gibson Emma K.34ORCID,Morgan David J.1ORCID,Jones Wilm3ORCID,Wells Peter P.3456ORCID,Johnston Peter7ORCID,Catlow C. Richard A.134,Kiely Christopher J.2ORCID,Hutchings Graham J.1ORCID

Affiliation:

1. Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, UK.

2. Department of Materials Science and Engineering, Lehigh University, 5 East Packer Avenue, Bethlehem, PA 18015, USA.

3. UK Catalysis Hub, Research Complex at Harwell, Rutherford Appleton Laboratory (RAL), Oxford OX11 0FA, UK.

4. Kathleen Lonsdale Building, Department of Chemistry, University College London, Gordon Street, London WC1H 0AJ, UK.

5. School of Chemistry, University of Southampton, Southampton SO17 1BJ, UK.

6. Diamond Light Source, Harwell Science and Innovation Campus, Chilton, Didcot OX11 0DE, UK.

7. Process Technologies, Johnson Matthey PLC, Billingham TS23 1LB, UK.

Abstract

Gold-on-carbon catalysts are analogs of homogeneous gold catalysts that use a redox couple of Au(I) and Au(III) species.

Funder

National Science Foundation

Engineering and Physical Sciences Research Council

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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