A study on the kinetics of ozone decomposition in waters of different quality

Abstract

The kinetics of ozone decomposition in waters of different quality, namely distilled water, tap water previously treated with ozone, tap water not treated with ozone and raw water from an accumulation lake, were studied in a batch stirred reactor at different temperatures (18-28?C). The dissolved ozone concentration was measured by the iodometric titration method. It was determined that an empirical kinetic equation of the form: dc(O3)/dt= k0 + k1c(O3) fitted the experimental data better than a first-order reaction rate equation. The apparent reaction rate constants in the case of ozone decomposition in distilled water were shown to be a function of temperature in accordance with the Arrhenius equation.