Determination of glass transition temperature and surface properties of novel chalcone modified poly (styrene) based polymer

Author:

Adiguzel Aysegul1,Cakar Fatih2,Senkal Bahire3,Cankurtaran Ozlem2,Gursel Yesim3,Karaman Ferdane2

Affiliation:

1. Bursa Technical University, Department of Chemistry, Bursa, Turkey + Yıldız Technical University, Department of Chemistry, İstanbul, Turkey

2. Yıldız Technical University, Department of Chemistry, İstanbul, Turkey

3. Istanbul Technical University, Department of Chemistry, İstanbul, Turkey

Abstract

The novel chalcone modified poly (styrene) based polymer (PVBC-DMAC) has been prepared and characterized. By using the inverse gas chromatography method, we determined glass transition temperature and surface properties of PVBC-DMAC. The obtained glass transition temperature, Tg, is a good agree with the one obtained by differential scanning calorimetry. Also considering some isomeric alcohol and acetate solvents in the temperature range from 303.2 K to 353.2 K, we investigated the polymer selectivity. The parameters KA(acidic) and KD(basic) of the PVBC-DMAC surface were calculated. The obtained KA, KD values reflected that PVBC-DMAC surface has a basic character.

Publisher

National Library of Serbia

Subject

Renewable Energy, Sustainability and the Environment

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