1. This catalyst demonstrated the highest TOF value of 454.06 mol H2 mol Pt min -1 and the activation energy of 41.82 kJ mol -1 at 25 ?. Moreover, the excellent catalytic activity of NiTi-LDH@B 12 H 12 @Pt 2.4% can be attributed to several factors, including the mild reducibility of [closo-B 12 H 12 ] 2-, the small particle size and uniform distribution of Pt clusters (2.49 nm), large specific surface area (210.568 m 2 /g), and the synergistic catalytic effect of Pt and NiTi-LDH that accelerates electron transfer. Furthermore, the catalytic hydrolysis of AB are1.15-order and 0.24-order dependence on Pt and AB concentrations, respectively. Moreover, NiTi-LDH@B 12 H 12 @Pt 2.4% demonstrates excellent catalytic performance after five cycles. The facile preparation method, excellent catalytic and reusability make NiTi-LDH@B 12 H 12 @Pt 2.4% a green catalyst for AB hydrolysis with good application prospects. The strategy and method described here have good reference and inspiration for the design and application of catalysts;CRediT authorship contribution statement Haixu Zhao: Writing -original draft, Investigation. Weikang Zhang: Writing -review & editing. Chaoran Liao: Writing -review & editing. Zhuodong Ou: Investigation. Zhanhao Liang: Investigation. Lin Hui: Investigation. Xuefan Deng: Writing -review & editing, Supervision, Project administration, Conceptualization. Long Zhang: Writing -review & editing
2. An amorphous FeMoS 4 nanorod array toward efficient hydrogen evolution electrocatalysis under neutral conditions;X Ren;Chemical Communications,2017
3. Enhanced Activity of Visible Light Photocatalytic H 2 Evolution of Sulfur-Doped g-C 3 N 4 Photocatalyst via Nanoparticle Metal Ni as Cocatalyst;C Sun;Applied Catalysis B: Environmental,2018
4. Predicting hydrogen storage capacity of metal-organic frameworks using group method of data handling;S Atashrouz;Neural Computing & Applications,2020
5. Light metal borohydrides/amides combined hydrogen storage systems: composition, structure and properties;S Qiu;Journal of Materials Chemistry A,2017