Interacting semi-flexible self-avoiding walks studied on a fractal lattice

Abstract

Abstract Self-avoiding walks are studied on the 3-simplex fractal lattice as a model of linear polymer conformations in a dilute, nonhomogeneous solution. The model is supplemented with bending energies and attractive-interaction energies between nonconsecutively visited pairs of nearest-neighboring sites (contacts). It captures the main features of a semi-flexible polymer subjected to variable solvent conditions. A hierarchical structure of the fractal lattice enabled the determination of the exact recurrence equations for the generating function, through which universal and local properties of the model were studied. An analysis of the recurrence equations showed that for all finite values of the considered energies and nonzero temperatures, the polymer resides in an expanded phase. The critical exponents of the expanded phase are universal and the same as those for ordinary self-avoiding walks on the same lattice found earlier. As a measure of local properties, the mean number of contacts per mean number of steps as well as the persistence length, are calculated as functions of Boltzmann weights associated with bending energies and attractive interactions between contacts. Both quantities are monotonic functions of stiffness weights for fixed interaction, and in the limit of infinite stiffness, the number of contacts decreases to zero, while the persistence length increases unboundedly.