Nonlinear self-action of ultrashort guided exciton–polariton pulses in dielectric slab coupled to 2D semiconductor

Abstract

Abstract Recently reported large values of exciton–polariton nonlinearity of transition metal dichalcogenide (TMD) monolayers coupled to optically resonant structures approach the values characteristic for GaAs-based systems in the regime of strong light-matter coupling. Contrary to the latter, TMD-based polaritonic devices remain operational at ambient conditions and therefore have greater potential for practical nanophotonic applications. Here, we present the study of the nonlinear properties of Ta2O5 slab waveguide coupled to a WSe2 monolayer. We confirm that the hybridization between the waveguide mode and the exciton resonance in WSe2 gives rise to the formation of guided exciton–polaritons with Rabi splitting of 36 meV. By measuring transmission of ultrashort optical pulses through this TMD-based polaritonic waveguide, we demonstrate the strong nonlinear dependence of the output spectrum on the input pulse energy. We develop a theoretical model that shows agreement with the experimental results and gives insights into the dominating microscopic processes which determine the nonlinear pulse self-action: Coulomb exciton–exciton interaction and scattering to an incoherent excitonic reservoir. Based on the numerical simulation of nonlinear phenomena in our polariton system, we conclude that it may support a quasi-stationary solitonic regime of pulse propagation at intermediate pump energies. Our results provide an important step for the development of nonlinear on-chip polaritonic devices based on 2D semiconductors.