Synthesis, structure, and magnetic properties of the quaternary oxysulfides Ln 5V3O7S6 (Ln = La, Ce)-Reference-Cited by-同舟云学术

Synthesis, structure, and magnetic properties of the quaternary oxysulfides Ln 5V3O7S6 (Ln = La, Ce)

Published:2021-09-22 Issue:10-12 Volume:76 Page:677-688
ISSN:0932-0776
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Zheng Chong¹^ORCID,Hoffmann Roald²,Perkins Timothy S.³,Calvagna Frank⁴,Fotovat Roxanna¹,Ferels Crystal¹,Mohr Alyssa¹,Kremer Reinhard K.⁵,Köhler Jürgen⁵,Simon Arndt⁵,Bu Kejun⁶,Huang Fuqiang⁶

Affiliation:

1. Department of Chemistry and Biochemistry , Northern Illinois University , DeKalb , IL , 60115 , USA

2. Department of Chemistry and Chemical Biology , Cornell University , Ithaca , New York 14853 , USA ,

3. Department of Chemistry , Coker University , Hartsville , SC , 29550 , USA

4. Department of Chemistry , Rock Valley College , Rockford , IL , 61114 , USA

5. Max-Planck-Institut für Festkörperforschung , Heisenbergstrasse 1 , D-70569 Stuttgart , Germany

6. Shanghai Institute of Ceramics , Chinese Academy of Sciences , Shanghai , 200050 , P. R. China

Abstract

Abstract Two rare earth oxysulfides Ln 5V3O7S6 (Ln = La, Ce) have been synthesized and their structures determined. The two isostructural compounds crystallize in the orthorhombic space group Pmmn (no. 59). The structure features one-dimensional edge-sharing VS4O2 octahedron chains parallel to the b axis. The bonding between V and S/O is covalent, and between Ln 3+ and the rest of the matrix ionic. Magnetic susceptibility measurement revealed that V is in a mixed valence state of V3+ and V4+. Its magnetic behavior follows the Curie-Weiss law.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-2021-0107/pdf

Reference124 articles.

1. Dugue, J., Tien, V., Laruelle, P. Acta Crystallogr. 1985, C41, 1146–1148; https://doi.org/10.1107/s0108270185006928.

2. Disalvo, F. J. Sci. 1990, 247, 649–655; https://doi.org/10.1126/science.247.4943.649.

3. Flahaut, J. Sulfides, selenides and tellurides. In Handbook on the Physics and Chemistry of Rare Earths; Gschneidner, K. A. Jr., Eyring, L. R., Eds. North-Holland Publishing Company: New York, Vol. 4, 1979, pp. 1–88. chapter 31.

4. Ibañez, R., Garcia, A., Fouassier, C., Hagenmuller, P. J. Solid State Chem. 1984, 53, 406–414; https://doi.org/10.1016/0022-4596(84)90119-1.

5. Kolesov, B. A., Vasilyeva, I. G. Mater. Res. Bull. 1992, 27, 775–781; https://doi.org/10.1016/0025-5408(92)90086-f.