[RuCl2(dppf)(PN)]/Pd-cocatalyzed three-component synthesis of 2-pyridinyl-6-arylquinolines
Author:
Wang Hao1, Bai Pengtao1, Wen Shuo1, Wei Jingjing1, Song Heng1, Xu Chen1
Affiliation:
1. School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology , Zhenjiang , Jiangsu 212100 , P.R. China
Abstract
Abstract
A new complex [RuCl2(dppf)(PN)] 1 (dppf = 1,1′-bis(diphenylphosphino) ferrocene; PN = (2-diphenylphosphino)benzenamine) has been synthesized and characterized. Its structure was determined by single-crystal X-ray diffraction. An efficient 1/Pd salt-cocatalyzed three-component oxidation/cyclization/Suzuki reaction for the synthesis of 2-pyridinyl-6-arylquinolines from 2-acetylpyridine, (2-amino-5-bromophenyl)methanol, and arylboronic acids has been developed.
Publisher
Walter de Gruyter GmbH
Subject
General Chemistry
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