Metal and Boron Derivatives of Fluorinated Cyclic 1,3-Dicarbonyl Compounds-Reference-Cited by-同舟云学术

Metal and Boron Derivatives of Fluorinated Cyclic 1,3-Dicarbonyl Compounds

Published:2009-05-01 Issue:5 Volume:64 Page:541-550
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Sevenard Dmitri V.¹,Khomutov Oleg G.²,Boltachova Nadezhda S.²,Filyakova Vera I.²,Vogel Vera³,Lork Enno³,Sosnovskikh Vyacheslav Ya.⁴,Iaroshenko Viktor O.⁵,Röschenthaler Gerd-Volker³

Affiliation:

1. Hansa Fine Chemicals GmbH, BITZ, Fahrenheit Straße 1, 28359 Bremen, Germany

2. Institute of Organic Synthesis, Russian Academy of Sciences, Ural Branch, S. Kovalevskoy Street 22, GSP-147, 620041 Ekaterinburg, Russian Federation

3. Institute of Inorganic & Physical Chemistry, University of Bremen, Leobener Straße, 28334 Bremen, Germany

4. Department of Chemistry, Ural State University, Lenina 51, 620083 Ekaterinburg, Russian Federation

5. National Taras Shevchenko University, 62 Volodymyrska Street, Kyiv-33, 01033, Ukraine

Abstract

Starting from the corresponding cyclic 1,3-diketones or other precursors (cyclic ketones as well as lactones), several new salts and chelate complexes of fluorinated 1,3-dicarbonyls were obtained. Their preparative significance was demonstrated by straightforward syntheses of fluorinated pyrazoles, benzimidazoles and 1,7-ketoesters. The structure of a boron chelate of 2-(trifluoroacetyl)- cyclohexanone was investigated by X-ray diffraction.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-2009-0510/pdf

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