Author:
Weber Marcus,Schlesinger Maik,Walther Markus,Zahn Dirk,Schalley Christoph A.,Mehring Michael
Abstract
AbstractInvestigations on bismuth oxido clusters are focused on the nucleation and growth processes towards large cluster motifs and their stability in the gas phase, which has been studied by electrospray ionization mass spectrometry (ESI-MS), molecular dynamics (MD) simulations and X-ray scattering experiments evaluated by pair distribution function (PDF) analysis. The formation of metastable bismuth(III) oxides was obtained by hydrolysis of polynuclear bismuth oxido clusters and subsequent thermal treatment under non-equilibrium conditions. Temperature dependent PXRD and Raman spectroscopic experiments gave insight into the formation process of metastable β-Bi
Subject
Inorganic Chemistry,Condensed Matter Physics,General Materials Science
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