Color control of titanium nitride thin films

Author:

Ontoria Aian B.1ORCID,Vasquez Magdaleno R.1ORCID

Affiliation:

1. Department of Mining, Metallurgical, and Materials Engineering, College of Engineering, University of the Philippines , Diliman, Quezon City 1101, Philippines

Abstract

Titanium nitride (TiN) films were deposited on 304 stainless steel substrates using a radio frequency-powered magnetron sputtering system. The influence of the argon:nitrogen gas ratio (90:10, 80:20, 70:30) and the substrate temperature (room temperature, 200 °C, 400 °C) were investigated. X-ray diffractograms revealed a crystal orientation along the (111) plane with lattice parameters ranging from 4.268 to 4.319 Å. Colorimetric analysis of the deposited films revealed a color difference (ΔEab∗) from actual gold that ranged from 2.6 to 33.2. The hardness data of the TiN-coated (ΔEab∗=2.6) revealed a 53% increase compared to the bare substrates. 300-h salt spray test showed no significant corrosion for the TiN-coated substrates. With a gold-like finish coupled with excellent mechanical properties, the TiN films can be used as a durable decorative coating for the creative industries.

Funder

Department of Science and Technology, Philippines

Publisher

American Vacuum Society

Subject

Materials Chemistry,Electrical and Electronic Engineering,Surfaces, Coatings and Films,Process Chemistry and Technology,Instrumentation,Electronic, Optical and Magnetic Materials

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